Toward a Digital Twin for Frontal Polymerization-based Manufacturing: From Multiphysics Modeling to Real-Time Monitoring and Control
Frontal polymerization (FP) is an energy-efficient manufacturing approach in which a localized initiation triggers a self-propagating exothermic reaction front that rapidly cures thermoset polymers and composites. This unique mechanism enables fast curing and free-standing fabrication, but it also creates challenges for process design because the thermal, chemical, and mechanical fields are strongly coupled, process outcomes are sensitive to boundary conditions and operating parameters, and key internal states such as cure degree are difficult to observe directly during manufacturing. In this talk, Zhang will present recent efforts toward a digital twin for FP-based manufacturing, emphasizing the progression from physics-based understanding to real-time process monitoring and control. He will begin with an introduction to FP and early experimental and modeling studies from his postdoctoral work at the University of Illinois Urbana- Champaign, which helped establish the foundation for FP-enabled manufacturing and direct ink writing. Developments at the University of Wyoming will be discussed, including thermo-chemical modeling of layer-by-layer FP printing and thermo-chemo- mechanical modeling of process-induced residual deformation, which together clarify how front behavior, cure evolution, and thermal history influence manufacturing quality. Building on this foundation, Zhang will present recent work on digital-twin-guided closed-loop print-speed control and on real-time cure-state estimation from infrared thermography using cascaded inverse-forward deep learning with uncertainty quantification. Finally, he will highlight emerging manufacturing demonstrations, including lattice structures and lunar regolith-reinforced composites, and outline a path toward digital twins that support real-time monitoring, adaptive control, and ultimately process optimization in FP-based polymer and composite manufacturing.